| |
Nd:GeVO 4
Nd:GdVO4, grown with Czochralski method, is a promising laser crystal for diode
pumped lasers. Similar to Nd:YVO4, It exhibits high absorption and large
emission cross section. In fact, Nd:GdVO4 has a 7-times higher absorption cross
section at 808nm and a 3-times larger emission cross section at 1.06µm than
those of Nd:YAG. In addition, Nd:GdVO44has
much high thermal conductivity compared to Nd:YVO4.
In each case of cw
laser performance at 1.06µm and 1.34µm and intracavity doubling with KTP and LBO,
Nd:GdVO4 has a high slope efficiency or optical conversion efficiency compared
to Nd:YVO4.
Physical Properties:
|
Nd3+
Concentration |
1.0±
0.1at.%
|
|
Structure |
Zircon
Tetragonal, space group D4h-I4/amd, a=b=7.212, c=6.350
|
|
Space
Group |
I41/amd
|
|
Density |
5.48g/cm3 |
|
Mohs
hardness |
4.6-5 |
|
Thermal
Conductivity |
11.7W/(mxK),
<110> |
Optical Properties:
|
Lasing
Transition |
4F3/2
–4I11/2
|
|
Lasing
Wavelength |
1062.9nm
|
|
Emission
Cross Section, (E
½½
c, at 1064 nm)
|
7.6x10-19cm2
|
|
Absorption Cross Section,
(E ½½c,
at 808 nm) |
4.9x10-19cm2 |
|
Linewidth |
3 nm
|
|
Relaxation Time of Terminal Lasing Level |
100ms |
|
Absorption Coefficient,
(E
½½
c, at 808 nm) |
74cm-1
|
In comparison with
similar laser crystals:
|
|
Nd:YVO4 |
Nd:GdVO4 |
Nd:YAG |
|
Laser
wavelength |
1064.3nm |
1062.9
nm |
1064.2nm |
|
1342.0
nm |
~1340 nm |
1338.2
nm |
|
Emission bandwidth
|
0.8 nm
|
No data |
0.45 nm |
|
Effective laser cross section
@ 1064 nm |
15.6 x
10-19 cm-2
|
7.6 x 10-19cm-2 |
6.5 x 10-19
cm-2 |
|
Polarization |
Parallel
to c-axis |
Parallel
to c-axis |
unpolarized |
|
Radioactive lifetime (1%Nd dopant) |
~ 100 µs
|
~ 95 µs
|
230
µs |
|
Pump
wavelength |
808.5 nm |
808.4 nm |
807.5 nm
|
|
Peak
pump absorption (1%Nd dopant) |
~ 41 cm-1
|
~ 57 cm-1
|
|
|
Thermal
conductivity |
5.1W/mK
|
11.7W/mK |
14W/mK |
|
Nd
concentration range |
0.1 -
3.0% |
0.1 -
3.0% |
0.1 -
2.0% |
Specifications:
|
Wavefront Distortion |
< l/8 at 633
nm |
|
Scattering |
invisible, probed with a He-Ne laser
|
|
Dimensional tolerance
|
+0.1/-0.1 mm |
|
Orientation tolerance |
+/-0.5° |
|
Surface quality |
10/5 S/D per MIL-O-13830A |
|
Flatness |
l/10 at 633 nm |
|
Clear Aperture |
> Central 90% |
|
Parallelism |
< 10 arc sec. |
HR/AR Coating: S1:
HR@1064&532nm
HT@808nm
S2:
AR@1064&532nm
AR/AR Coating: S1:
AR@1064nm&532nm
HT@808nm
S2:
AR@1064&532nm |